Most insurances don't pay out unless something bad happens to you that you wouldn't voluntarily do – even the job loss insurances (from governments, credit cards, etc.) only pay out on involuntarily unemployment, not if you quit or change jobs on your own accord.
A career change insurance would just be used by anyone unhappy with their current jobs (which is most people, some of the time, and a few people, all the time). The insurer would go bankrupt in a few weeks.