The first paragraph of the Radiosonde Wikipedia article[1] sums up the differences well.
Low-Earth orbit satellites receive GNSS signals that have passed through and been refracted by the atmosphere. The level of refraction is dependent on the pressure, temperature, and water vapor concentration in the lower atmosphere and the electron density in the ionosphere.
--
... which seems like they would benefit from weather balloons (or another source) collecting that data first as a baseline. Anyhow, one other thing that weather balloons collect is winds aloft (which is kind of a big deal in aviation for flight planning). Tomorrow's website mentions they can get near-surface wind speeds but that's not good enough.
https://spire.com/blog/maritime/radio-occultation-in-less-th...