What software features do you suspect might be buggy and that you would avoid when doing something important?
And do you think doing this is rational?
For me it is very rational to avoid some of too complicated features in software even if there weren't any bugs have been obserwed before. Especially if software is new and/or proprietary or if I'm working on something important or software has a Turing Mashine in it (Ethereum's Solidity, CSS3, macroses from MS Office etc). Another thing avoided to trust is any software "random" number generator if you have an access to coin or dice for accomplishing your task. Last but not least is not trusting to any connected device at all. So, I do not trust any software if to be honest and I hope my fear might be considered as rational.
It's a perfectly rational response to all the times we've been bitten by software in the past. (Though I've personally crashed a slot machine, so I may be more cautious than the average bear.)